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In fact, PCs are non-ribosomal peptides and are synthesized enzymatically (not by translation of mRNA owing to the presence of -carboxamide linkage between Glu and Cys) in response to varied metals from GSH by phytochelatin synthase (PCS), which is a -Glu-Cys dipeptidyl transpeptidase (E.C.2.3.2.15) (Vatamaniuk et al., 2004)

doi: 10.1016/j.intimp.2017.11.013 50 EndaleMParkSCKimSKimSHYangYChoJYet al

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