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Thiols such as GSH are strong antioxidants due to their ability to exist in either thiol or disulfide forms the former of which can form adducts with or reduce radical melanin intermediates 25,26

Functional studies confirmed that ferroptosis inducers such as erastin and RSL3 activated this signature in TNBC cells (MDA-MB-231), indicating that ferroptosis may reshape ECM dynamics and the tumor microenvironment ( In pregnancy disorders, the HMGB1-ferroptosis axis contributes to placental dysfunction