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S13B) were observed in the L-DKO mice

Although RpiA and RpiB are structurally very different, both enzymes catalyze the isomerization reaction via an enediol intermediate, using the linear form of the sugar

We provide evidence that GSH indeed plays a key role in disulfide bond formation and redox homeostasis in the periplasm: We observed that GSSG can complement for the loss of DsbA and, unexpectedly, that GSH accelerates disulfide bond formation in the presence of DsbA

The proposed mechanism by which HCC was not affected by SAMe in this model is due to compensatory induction of methyltransferases (mainly GNMT) in the normal hepatic tissue to prevent supraphysiologic accumulation of SAMe