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Acknowledgements We would thank Professor Shuang Wang, Clinician Hui Chen (Department of Pathology, Nanfang Hospital), Dr

On the other hand, the structure of the second conformer aqII is stabilized by two hydrogen interactions: between the Dtryptophan's carbonyl group and the terminal NH 2

Conversely, in specific microenvironments (e.g., the weakly acidic tumor microenvironment or sites of bacterial infection) or in the presence of specific substrates, their POD-like (converting H 2 O 2 to OH under acidic conditions) and OXD-like activities are activated