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Nicotinamide N-methyltransferase (NNMT), an enzyme involved in fat synthesis and energy metabolism, is inhibited by 5-Amino-1MQ

The tar phase of the cigarette smoke contains organic radicals that react with molecular oxygen to form - , and H 2 O 2

While in the absence of light, the inhibition is released, allowing for the synthesis of melatonin as the SCN activity drops, which allows the paraventricular nucleus to start activating the intermediolateral cell column, which in turn activates the superior cervical ganglion and finally postganglionic fibers that directly affect the pineal gland with the help of norepinephrine that binds to 1 -adrenergic receptors to start melatonin synthesis (178)