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Thiol-disulfide balance: From the concept of oxidative stress to that of redox regulation

Inhibition of GPX4whether pharmacologically (e.g., by erastin or RSL3) or via GSH depletionleads to lipid peroxide accumulation, membrane disruption, and ferroptotic death ( Ferroptosis is defined by three core biochemical events: (i) PUFA-phospholipid oxidation, (ii) the presence of redox-active iron, and (iii) compromised antioxidant defenses, particularly GSH and GPX4 ( Figure 1 )

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