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doi: 10.1016/j.nut.2018.02.005

Enzymatic demethylation of 7,8-dihydromethysticin followed by ring opening of the alpha-pyrone ring, and rearrangement was suggested to contribute to the formation of highly GSH reactive metabolite 6-phenyl-3-hexen-2-one as its mercapturic acid adduct found in human urine [43]