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It's not about brute force

-bond The unusual gamma peptide bond between glutamate and cysteine atypical in biology, intentional in chemistry The bond between the first two amino acids in glutathione is a gamma-bond rather than the standard alpha-bond used in most peptide chemistry

Instead, we utilised the high nucleophilic reactivity of RSS and RS(S) n S (due to their low pK a and the -effect of the non-terminal sulfur atom) that enables reaction with iodoacetamide (IAM) to generate reaction products that incorporate the terminal sulfane sulfur (Fig

Prkov forma zabezpeuje jednoduch dvkovanie sta ho zmiea s vodou alebo obbenm npojom a uva poda potreby, pred trningom alebo poas da